This paper presents a comparative analysis of women's educational attainment across the BRICS nations (Brazil, Russia, India, China, and South Africa), examining the nexus between educational output and labour market integration. The research confirms that concerted government action, including high investment and affirmative policies, has resulted in significant success, particularly at the tertiary level, leading to a "parity reversal" where female enrolment often exceeds male enrolment in high-attainment countries like China, Brazil, and Russia. Despite these impressive quantitative achievements, a persistent "paradox of attainment" exists: translating educational gains into equitable employment proves difficult. High female unemployment in countries such as Brazil and South Africa highlights deep-seated socio-economic and structural challenges beyond mere access to schooling. Governments are responding by shifting policy focus toward the quality and relevance of education through aggressive investment in Science, Technology, Engineering, and Mathematics (STEM) and digital skill training. To fully capitalize on this valuable human capital, the study concludes that robust labour market reforms, targeted job creation, and the vigorous enforcement of anti-discrimination laws are essential to combat structural inequality and close the enduring employment gap.